The research team led by the University of Tsukuba has successfully developed a new method that can prevent the crossover of large fuel molecules and suppress the degradation of electrodes in advanced fuel cell technology using methanol or formic acid. The successful sieving of the fuel molecules is achieved via selective proton transfers due to steric hindrance on holey graphene sheets that have chemical functionalization and act as proton-exchange membranes.

Tsukuba, Japan—For realizing carbon neutrality, the demand for the development of direct methanol/formic acid-fuel cell technology has been increasing. In this technology, methanol or formic acid is used as an e-fuel for generating electricity. The fuel cells generate electricity via proton transfer; however, conventional proton-exchange membranes suffer from the "crossover phenomenon," where the fuel molecules are also transferred between anodes and cathodes. Thereafter, the fuel molecules are unnecessarily oxidized and the electrodes are deactivated. In this study, the researchers developed a new proton-exchange membrane comprising graphene sheets with 5-10 nm-diameter holes, which are chemically modified with sulfanilic functional groups affording sulfo groups around the holes. Owing to steric hindrance by the functional groups, the graphene membrane successfully suppresses the crossover phenomenon by blocking the penetration of the fuel molecules while maintaining high proton conductivity for the first time to the best of our knowledge.

To date, conventional approaches for inhibiting fuel-molecule migration involved an increase of the membrane thickness or sandwiching two-dimensional materials, which in turn reduced the proton conductivity. In this study, the researchers investigated structures that inhibit the migration of fuel molecules through electro-osmotic drag and steric hindrance. Consequently, they found that the sulfanilic-functionalized graphene membrane can remarkably suppress electrode degradation compared with the commercially-available Nafion membranes while maintaining the proton conductivity required for fuel cells.

Furthermore, simply pasting the graphene membrane onto a conventional proton-exchange membrane can suppress the crossover phenomenon. Thus, this study contributes to the development of advanced fuel cells as a new alternative for hydrogen-type fuel cells.

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JST-PRESTO (JPMJPR2115), the Mukai science and technology foundation, the JSPS Grant-in-Aid for Scientific Research on Innovative Areas "Discrete Geometric Analysis for Materials Design" (Grant Numbers JP20H04628, JP20H04639), JSPS KAKENHI (Grant Numbers JP21H02037, JP21KK0091, JP23K17661), and a cooperative program (Proposal No. 202111-CRKEQ-0001) of CRDAM-IMR, Tohoku University.

Original Paper

Title of original paper:

Suppression of Methanol and Formate Crossover through Sulfanilic-functionalized Holey Graphene as Proton Exchange Membranes

Journal:

Advanced Science

DOI:

10.1002/advs.202304082

Correspondence

Assistant Professor Jeong Samuel
Associate Professor ITO Yoshikazu
Institute of Pure and Applied Science, University of Tsukuba

Associate professor OHTO Tatsuhiko
Graduate School of Engineering, Nagoya University

Assistant Professor NISHIUCHI Tomohiko
Graduate School of Science, Osaka University

Related Link

Institute of Pure and Applied Sciences